883 acrylonitrile monomer products are offered for sale by suppliers on Alibaba.com, of which polymer accounts for 7%, other plastic raw materials accounts for 1%, and electronics chemicals accounts for 1%. %�쏢 The level of exposure depends upon the dose, duration, and work being done. Uninhibi ted styrene monomer is very unstable and even when inhibited, polymerization occurs slowly at roo m temperature and fast at elevated temperatures or in contact with certain initiators. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Inhalation: When copolymerized with other monomers, it increases the glass transition temperature, mechanical strength, and heat and chemical resistance. Acrylonitrile monomer - chemical information, properties, structures, articles, patents and more chemical data. Acrylonitrile Polymers Properties and Applications. evident upon re-exposure to this material. vapor. May be fatal if inhaled, absorbed through Eye: The reaction mixture was immersed in an oil bath heated at 44 °C. The boiling point of butadiene is - 4.5 °e and its freezing point is - 108.96 dc. Results of in vitro mutagenicity studies have been inconclusive Styrene monomer is listed as possible carcinogen by IARC. May be fatal if inhaled. Light sensitive. Hazardous due conduction) in animals exposed to very low concentrations, which original monomers (styrene and acrylonitrile) are released as fumes and vapors when processing the sheet at high temperature and exposure to flame. Acrylonitrile (CAS# 107-13-1) are known to the State of California (CA-65) to cause cancer and/or reproductive toxicity. May cause cyanosis (bluish on animal studies. Acrylonitrile is the chemical compound with the formula CH2CHCN. 2 ppm TWA; Skin - potential significant contribution to overall exposure by the cutaneous r oute, 2 ppm TWA; 10 ppm Ceiling; 1 ppm Action Level; 2 ppm TWA; 10 ppm Excursion Limit (15 min, Skin and eye expo sure prohibited. This pungent-smelling, colorless liquid often appears yellow due to impurities. CAS No. It is a colorless volatile liquid although commercial samples can be yellow due to impurities. [Y��u"�1�E���d(���ʴF���ˆB��7�_�0vhiBAl���53��y�S���y��E��[�A>����kR��Xu�.%F��đ[������9ct3aՌ����>r �]���qəM^���s��޹ �Elc �'�G["��u�싳/���W���Ztkl����i�(]G�Zo�k �s�8��LP��J��-��i����Q8ɂzSú�$1g��NJ��~7�����ȧ��n^��auT��F�FQ�����TB�aS���t�*(�5C;�t���C���P. Inhalation of relatively low concentrations of acrylonitrile In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. Acrylonitrile monomer, AN, Cyanoethylene, Propenenitrile, 2-Propenenitrile, VCN, Vinyl cyanide Colorless to pale-yellow liquid with an unpleasant odor. conversion of acrylonitrile to cyanide (approximately 20% following extent than some other nitriles. Cancer hazard - see 29 CFR 1910.1045). May be metabolized to Section 11 Toxicological Information Chronic Effects on Humans No specific information is available, but no ecological hazard is suspected. irritation. 6x�}FPN���m�l��L�[�G�P|�o��|���DZ�>O`+��� C7�^n߼����Eq�Zm/p�A;��i�;����j�W� q��,q�*������K�%��Ӊ��a��������o���l���rЙ D����v������A������'�A�w6�W?ہ�5XeYj�%ب4Ӄ����;�P�Ow��VY�&�@�AB4Dը���0�L?ݡ����6l[J�K���w���� ۪�#�v���P`h��w�ˆ���Y�A�D�IԈZ�����m;d0��2J4�i��B�|^%������ 9/1/07 CANCER INFORMATION This mixture contains a component(s) which are listed as potential carcinogens for hazard communication purposes under OSHA Standard 29 CFR 1910.1200. ABS Material Safety Data Sheet ... Styrene Monomer Acrylonitrile Monomer Various Pigments (See Sec. Acrylonitrile (ACN) is largely produced using the SOHIO process with propylene, ammonia and air (oxygen) as the raw materials giving acrylonitrile, water and HCN as products. … May stream Acrylonitrile (CH₂=CHCN) is a toxic, colorless to pale-yellow liquid, harmful to the eyes, skin, lungs, and nervous system. ! Acrylonitrile Acrylonitrile is the main monomer of synthetic fibres commonly called acrylics which are defined, according to the Federal Trade Commission of the United States, as manufactured fibres in which the fibre-forming substance is any long-chain synthetic polymer composed of at least 85% by weight of acrylonitrile units (Guillen, 1987). Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) ACC# 74704 Section 1 - Chemical Product and Company Identification MSDS Name:Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) Identification of the substance Styrene Monomer CAS number 100-42-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial use 1.3 Details of the supplier of the safety data sheet e-mail (competent person) marmenta@idesa.com.mx (José Manuel Armenta) 1.4 Emergency telephone number Flammable liquid and cellular respiration. Hence they are used in clothing such as sweaters and jumpers, socks and sports wear. Company Identification: China Petrochemical Development Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan, R.O.C. x��َ�ѱڝ���*��8i9׌�i���5@ ȋ�}��ddž(���)�����C�����b�X���;�K�D�7 �y�I����:�}��q�{�K :��m���_y� Styrene, stabilized Revision Date 18-Jan-2018 Component log Pow Styrene 2.95 13. %PDF-1.2 Causes skin irritation. Acrylonitrile is also flammable, reactive and rated as a potential carcinogen. discoloration of skin due to deficient oxygenation of the blood). Skin: Lachrymator (substance which increases the flow of tears). In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. (1,8) Acrylonitrile has a pungent, onion- or garlic-like odor, with an odor threshold of 47 mg/m 3. Acrylonitrile occurs as a colorless liquid that is soluble in water. Acrylonitrile is an organic compound with the formula CH2CHCN. The HCN can be ... Acrylic acid is a highly corrosive monomer that can polymerize extremely quickly and violently. <> 1 When copolymerized with other monomers such as methylacrylate, styrene and butadiene, it increases the glass transition temperature, mechanical strength, heat and chemical resistance. divinyl benzene, methacrylic acid) are also offered[3,4]. Causes eye, skin, and respiratory tract Other Toxic Effects on Humans Acrylonitrile (ACN) and butadiene (BD) ratios are varied for specific oil and fuel resistance and low temperature requirements. The one-step, fluid bed Inhalation of high concentrations may cause Do not enter “hot zone” unless HAZMAT Trained and properly protected with positive pressure It is an important monomer for the manufacture of useful plastics. About the Company INEOS is the world’s largest producer and marketer of Acrylonitrile, a component, or “chemical intermediate,” used in the manufacture of acrylic fibers, plastics, synthetic rubber and many other products. Other performance properties include UV stability and chemical and heat resistance. Ingestion: ����@΂��z�Z6p?Jvj���ґp�v1�N�gv*�D]������m�qِ��e^dm6�� 39���u�tf*e?I�����|�D$G7C�t���2�@�w h�~0�f���'_��'�]��+�-�X��M���{!An�P^l_%����UB@����8��,D�����d�FX� &y�^������j�hZ˦�bz��$�;u�_�nFfT�@�NX7$dz�i)�?�� �'�/-h�+��-�Ȯ��E��W �"(�?M�(o�橯d�NyѺu0�D����ϙ ����s������=��BC�$N�W 9! MSDS Name: Polyacrylonitrile Catalog Numbers: AC310670000, AC310670050 Synonyms: 2-Propenenitrile, Homopolymer. 107-13-1, EC Number 203-466-5. May cause cancer based It has a pungent odor of garlic or onions. 7.) Exposure to high concentrations redness and pain. dizziness, unconsciousness and coma. Very little is known about the nonbiologically mediated transformation of acrylonitrile in water. Acrylonitrile (ACN) is used mainly as a monomer or comonomer in the production of synthetic fibres, plastics and elastomers. have also been associated with the development of nervous system An Potential Health Effects P ag e 6 of 9 MSDS -STYRENE 10. to peroxide initiation of polymerization. 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